BNCP 起爆药的合成及其主要性能

PyrotechnicsSeminar,FortР →[Co(NH3)4(NT)2]ClO4 +2NaClO4 +2H2O(6) CollinsColorado,15-19July1996.Р 关键技术是控制反应的 pH值、温度、反应时间和[3] GilliganW H,KamletM J.Synthesisofmercuric5niР母液浓度,控制不好仅得到微量产品。 trotetrazole[R].ADA036086,NSWC/WOL/TR76-Р (4)BNCP的起始分解温度比 CP低 20℃,有利 146,9,Dec.1976.Р于热桥丝发火和激光点火。[4] 盛涤伦.高氯酸·五氨·[2(5氰基四唑酸根)]合钴Р (Ⅲ)的制备[J].火工品,1991(4):1-6.Р 从表 1和表 2中可以看出:BNCP的撞击感度比Р StudyonSynthesisandMainPropertiesofBNCPР SHENGDilun,MAFenge,SUNFeilong,LüQiaoliР (ShanxiAppliedPhysicoChemistryResearchInstitute,Xi′an710061,China)Р Abstract:Amethodisintroducedtosynthesizeanewprimaryexplosive—tetraamminebis(5nitrotetrazoР lato)cobalt(Ⅲ)perchlorate(BNCP).Itsstructureisidentifedandsomepropertiesaredetermined.Р Keywords:tetraamminebis(5nitrotetrazolato)cobalt(Ⅲ)perchlorate(BNCP);synthesis;property