武汉大学化学学院期末试卷

12CH 3 NH (CH 2) 12CH 3 CH 3(CH 2) 6CH 2BrCH 3(CH 2) 6CH (CH 2) 12CH 3 Lindlar 催化剂H 2 TM 2. 6 3. OH NaOH ONa CH 3I OCH 3 OCH 3 H 2SO 4 SO 3 SO 3H OCH 3 SO 3H NO 2 O 2N HNO 3 H 2SO 4 H 2O, 加热 TM H 2SO 4 4 。 Br 2 Mg FeCl 3 Br MgBr O CH 2CH 2OH SOCl 2 CH 2CH 2ClMg CH 2CH 2MgCl CH 3COCH 3 CH 2CH 2C (CH 3 )2 OH TM H 2SO 4 四、 O CH 3 CH 3 C CH 3 CH 3 HOH 2CH 2C OH H C CH 3 CH 3 HOH 2CH 2C OH 2 -H 2O C CH 3 CH 3 HOH 2CH 2C O CH 3 CH 3 1. H H 2O The oxygen atom on the carbon 2 should most likely be eliminated, because after it is eliminated, the formed carbonium is on 3 o C, which is more stable than it on carbon 5, which is a 1 o carbon. + H OHOH 2 5 6 C (C H ) 2. C(C 6H 5) 2 OH 2 OH O C 6H 5 C 6H 5 -H O C 6H 5 C 6H 5 H H 2O 7 3. H H H 2O 五、1.A OC 2H 5; B. OH; C.C 2H 5I 2.CH 3 C H CH 3 CH 2OH