锂-氧化铜电池及其反应机理

. D. Raistriok , R. à. Huggins , J. 1~ 343(1980). [12J A. N. Dey , Th ìln Solid Fù 43 , 131(1977). 句邢雪坤,史美仑,陈民勤,吴浩青,化学学报 969 (1982). 226 化学学报卷 REACTION MECHANISMS IN LijCuO AND LijCU20 CELLS XING XUE-KU 旷 XIAO MING LIOHUANG Wu HA Q- QING 归,加 ABSTRAOT LijOuO and LijOUllO oe11s and disoharge meoha 丑 have been inve 的 by mea 卫 of severa1 no 时ωh 丑 XPS , ESR and X-ray 时皿 have show 丑古 in b 的 h he disoharge meoha 卫皿 are 忧。- ohemioa1 丑挝 on of u 皿 non1ayer oompounds , 丑 g 的一扫 on and breaking 也 Ou 一一 o bond , wi 由也 he separation of Cu. The resu1ts of oyolio voltamm 的 ry are in aooordanoe wi 由也 meohanism. Wi 也时协 p and ga1vano 供的。如 obnique the ohemioa1 diffusion 川 of L 俨丑 CuO and 旺 ee 的皿的 to be he order 皿 of 10- 12 皿矿'何=0.10