gh rate discharge performance and the cycle performance of electrode materials would be improved obviously.РAt last, we report a novel strategy for enhancing lithium ion transport by building superionic pathways on the surface of Li0.85Na0.15V3O8 nanosheets. The two-dimensional nanosheets were constructed by using a modified glycin acid sol-gel strategy and the electrode displayed a high rate capability of 172.3 mAh·g-1 at 5 C and an excellent cycling stability of retaining 98.9% after fifty cycles. Therefore, the strategy by building superionicРpathways on the surface of Li0.85Na0.15V3O8 nanosheets will be good for achieving high-performance LiV3O8 electrode material.РKeywords: Lithium vanadate; Sol-gel method; Cation doping; Lithium ion and aqueous lithium ion battery; Superionic pathway