UV光解处理VOCs的理论计算

-H414C4H8O2C-HO-H463C-CO=O491C-OC=O1mol乙酸乙酯完全转化为CO2和H2O需要2018年元月风量编制浓度董工处理后达到差值物质质量分子量摩尔数理论最低所需能量所需灯管数:185nm254nm差值偏差光电转化效率η灯管功率w释放能量w1kw=3600kj9%15013.548.6Kj35%15052.5189Kj个数键能8414kj/mol2345.6kj/mol2352kj/mol1724kj/mol15431.2kj/mol10000m3/h1000mg/m360mg/m3940mg/m39400g88.11g/mol106.68mol579426.63kj136066096kj数量惊人!!2720514080kj数量惊人!!749.37kj0.13%有机物的键能表真空紫外灯VUV波能量键键能KJ/mol波长nm能量kj/molC-C345.6185647C=C607254328C≡C829C-O352以降解乙酸乙酯为例:C=O724乙酸乙酯包括:键C-H414C4H8O2C-HO-H463C-CO=O491C-OC=O1mol乙酸乙酯完全转化为CO2和H2O需要2018年元月风量编制浓度董工处理后达到差值物质质量分子量摩尔数理论最低所需能量所需灯管数:185nm254nm差值偏差光电转化效率η灯管功率w释放能量w1kw=3600kj9%15013.548.6Kj35%15052.5189Kj个数键能8414kj/mol2345.6kj/mol2352kj/mol1724kj/mol15431.2kj/mol10000m3/h1000mg/m360mg/m3940mg/m39400g88.11g/mol106.68mol579426.63kj136066096kj数量惊人!!2720514080kj数量惊人!!749.37kj0.13%