microstructures Representative ICP structures: (A) smooth microspheres, (B) nanocubes, (C) microrods, (D) wheels, (E) nanorods, (F) nanospheres 7 Great feature:high flexibility General Synthesis Methods 8 Solvothermal synthesis 9 stainless steel autoclave Hermes, S. et al. J. Am. Chem. Soc. 2005, 127, 13744-13745 Simple Sensitive to synthetic conditions Time consuming MOF- 11 Microwave assisted methods 10 Yoo, Y. et al. Microporous Mesoporous Mater., 2009, 123, 100-106 Yoo, Y. et al. Chem. Commun., 2008, 21, 2441-2443 Rapid seeding under microwave Solvothermal secondary growth Advantages : Time saving Oriented, pattered and multi-layer growth Mechanically robust 30 seconds on amorphous carbon- coated AAO, 30 seconds on bare AAO Pattered growth of MOF-5 Multi-layer MOF Si
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