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金属有机骨架材料mofs及其应用

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Jean Stone Professor of Chemistry at UCLA . 催化剂气体储存吸附分离含氮杂环含羧基含氮杂环与羧基分层、扩散法水热法搅拌合成法多孔性大比表面积结构的多样性 MOFs 合成方法特点应用分类 Design and synthesis of an exceptionally stable and highly porous anic framework This synthesis is achieved by borrowing ideas from metal carboxylate cluster chemistry, where anic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxylates. Li, H. Eddaoudi, M. O'Keeffe, M. Yaghi, O. M. Nature 402, 276-279 (1999) MOF-5 一个空腔的结构图 MOF-5 的层结构图 MOF-5 的吸附性能 Interwoven anic Framework on a Periodic Minimal Surface with Extra-Large Pores Chen, B. L. Eddaoudi, M. Hyde, S. T. O'Keeffe, M. Yaghi, O. M. science 291, 1021-1023 (2001) Chen, B. L. Eddaoudi, M. Hyde, S. T. O'Keeffe, M. Yaghi, O. M. science 291, 1021-1023 (2001)

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