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有机化学讲义

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ane(X),(2)\r1-bromo-2-methylpropane(X),(3)2-bromopropane(S+E?),(4)\r2-bromo-2-methylpropane(S+E)h(b)sodiummethoxideunderSN2/E2conditionsi(1)\r1-bromobutane(Sprimarily),(2)1-bromo-2-methylpropane(S+E?),(3)\r2-bromopropane(S+E),(4)2-bromo-2-methylpropane(E)EvaluationWarning:ThedocumentwascreatedwithSpire.PDFfor.NET.\rProblem19(a)SN2JJljYklmn(b)ElJojYpmn(c)SN1J\rjYWmn(d)E2JojYWmn\rProblem20qrJ0stu?vwxjYJtmn(a)SN2(b)SN2(c)\rSNI\rSN1,SN2,E1,E2?\rChlorocyclohexane+KOHA+CyclohexeneE2\r1-Bromobutane+NaN3T1-AzidobutaneSN2\r1-Chloro-1-methylcyclohexane+CH3COOHAW1-MethylcyclohexylacetateSNI\r10.11yz{|If:EFJJI\r}~MMethylation\r^^€QCH3I\rBiologicalmethylatingreagentQS-Adenosylmethionine(S-‚}ƒ„SAM)\rI}~…†‡(Norepinephrine)+S-ˆ}ƒ„,‰†‡(Adrenaline)\rCH3BrQŠ‹ŒŽ\rQ‡†:NH2GSH:}~M‘’‡“

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